Organic Synthesis Highlights, Volume 1VCH, 1991 - 410 pages Like its predecessor, Organic Synthesis Highlights II surveys recent accomplishments and current trends in synthetic organic chemistry. Part I describes new methods and reagents including asymmetric carbon-carbon bond formation with metallocenes and with enzymes, via temporary silicon connections, and by means of carbohydrate complexes. Part II describes landmarks in the synthesis of natural products and surveys synthetic strategies to different classes of natural products. The forty essays in this volume bear witness to the creativity and talent which have led to the recent advances in the field. Both advanced students and researchers active in the field will welcome this as a source of ideas and inspiration. |
Table des matières
Methods Reagents and Mechanisms | 1 |
Chiral Sulfoxides in the Synthesis of Enantiomerically Pure Compounds | 14 |
Braun | 33 |
Droits d'auteur | |
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Expressions et termes fréquents
acetal Acta addition adduct affords aldehyde aldol alkylation amines amino Angew anion application Asymmetric Synthesis B. M. Trost carbon carbonyl CH3 CH3 CH3 H CH3 H3C Chem chemistry Chim chiral auxiliary chiral center Claisen rearrangement CO₂CH3 CO₂Et CO₂H CO₂Me CO₂R complex compounds converted cyclization cycloaddition Danishefsky derivatives diastereomer diastereoselective Diels-Alder reaction double bond E. J. Corey electrophilic enantiomerically pure enantioselective Engl enolate enzyme epoxide ester ether example fenestrane formation H₂C H3C CH3 H3CO hedron Lett Helv hydrolysis intermediate intramolecular ketone key step lactone leads Lewis acid method methyl mixture molecule natural product nucleophile OCH3 OH OH olefin optically active Organic Synthesis oxidation Pauson-Khand reaction Ph Ph prepared racemic reagents recently reduction regioselectivity ring route Seebach selectivity silyl SiMe3 starting material stereochemical stereocontrol stereoselectivity substituted Tetrahedron Lett tion vinyl yield он